Combining chlorination and sulfuration strategies for high-performance all-small-molecule organic solar cells

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Combining chlorination and sulfuration strategies for high-performance all-small-molecule organic solar cells. / Zhou, Ruimin; Yang, Chen; Zou, Wenjun; Abdullah Adil, Muhammad; Li, Huan; Lv, Min; Huang, Ziyun; Lv, Menglan; Zhang, Jianqi; Lu, Kun; Wei, Zhixiang.

In: Journal of Energy Chemistry, Vol. 52, 01.01.2021, p. 228-233.

Research output: Contribution to journalJournal articleResearchpeer-review

Harvard

Zhou, R, Yang, C, Zou, W, Abdullah Adil, M, Li, H, Lv, M, Huang, Z, Lv, M, Zhang, J, Lu, K & Wei, Z 2021, 'Combining chlorination and sulfuration strategies for high-performance all-small-molecule organic solar cells', Journal of Energy Chemistry, vol. 52, pp. 228-233. https://doi.org/10.1016/j.jechem.2020.04.041

APA

Zhou, R., Yang, C., Zou, W., Abdullah Adil, M., Li, H., Lv, M., Huang, Z., Lv, M., Zhang, J., Lu, K., & Wei, Z. (2021). Combining chlorination and sulfuration strategies for high-performance all-small-molecule organic solar cells. Journal of Energy Chemistry, 52, 228-233. https://doi.org/10.1016/j.jechem.2020.04.041

Vancouver

Zhou R, Yang C, Zou W, Abdullah Adil M, Li H, Lv M et al. Combining chlorination and sulfuration strategies for high-performance all-small-molecule organic solar cells. Journal of Energy Chemistry. 2021 Jan 1;52:228-233. https://doi.org/10.1016/j.jechem.2020.04.041

Author

Zhou, Ruimin ; Yang, Chen ; Zou, Wenjun ; Abdullah Adil, Muhammad ; Li, Huan ; Lv, Min ; Huang, Ziyun ; Lv, Menglan ; Zhang, Jianqi ; Lu, Kun ; Wei, Zhixiang. / Combining chlorination and sulfuration strategies for high-performance all-small-molecule organic solar cells. In: Journal of Energy Chemistry. 2021 ; Vol. 52. pp. 228-233.

Bibtex

@article{a597303a7a104284a1d6374d73dd2fa4,
title = "Combining chlorination and sulfuration strategies for high-performance all-small-molecule organic solar cells",
abstract = "Three small-molecule donors based on dithieno[2,3-d:2ʹ,3ʹ-dʹ]-benzo[1,2-b:4,5-bʹ] dithiophene (DTBDT) unit were designed and synthesized by side chain regulation with chlorinated or/and sulfurated substitutions (namely ZR1, ZR1-Cl, and ZR1-S-Cl respectively), along with a crystalline non-fullerene acceptor IDIC-4Cl with a chlorinated 1,1-dicyanomethylene-3-indanone (IC) end group. Energy levels, molar extinction coefficients and crystallinities of three donor molecules can be effectively altered by combining chlorination and sulfuration strategies. Especially, the ZR1-S-Cl exhibited the best absorption ability, lowest higher occupied molecular orbital (HOMO) energy level and highest crystallinity among three donors, resulting in the corresponding all-small-molecule organic solar cells to produce a high power conversion efficiency (PCE) of 12.05% with IDIC-4Cl as an acceptor.",
author = "Ruimin Zhou and Chen Yang and Wenjun Zou and {Abdullah Adil}, Muhammad and Huan Li and Min Lv and Ziyun Huang and Menglan Lv and Jianqi Zhang and Kun Lu and Zhixiang Wei",
year = "2021",
month = jan,
day = "1",
doi = "10.1016/j.jechem.2020.04.041",
language = "English",
volume = "52",
pages = "228--233",
journal = "Journal of Natural Gas Chemistry",
issn = "2095-4956",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Combining chlorination and sulfuration strategies for high-performance all-small-molecule organic solar cells

AU - Zhou, Ruimin

AU - Yang, Chen

AU - Zou, Wenjun

AU - Abdullah Adil, Muhammad

AU - Li, Huan

AU - Lv, Min

AU - Huang, Ziyun

AU - Lv, Menglan

AU - Zhang, Jianqi

AU - Lu, Kun

AU - Wei, Zhixiang

PY - 2021/1/1

Y1 - 2021/1/1

N2 - Three small-molecule donors based on dithieno[2,3-d:2ʹ,3ʹ-dʹ]-benzo[1,2-b:4,5-bʹ] dithiophene (DTBDT) unit were designed and synthesized by side chain regulation with chlorinated or/and sulfurated substitutions (namely ZR1, ZR1-Cl, and ZR1-S-Cl respectively), along with a crystalline non-fullerene acceptor IDIC-4Cl with a chlorinated 1,1-dicyanomethylene-3-indanone (IC) end group. Energy levels, molar extinction coefficients and crystallinities of three donor molecules can be effectively altered by combining chlorination and sulfuration strategies. Especially, the ZR1-S-Cl exhibited the best absorption ability, lowest higher occupied molecular orbital (HOMO) energy level and highest crystallinity among three donors, resulting in the corresponding all-small-molecule organic solar cells to produce a high power conversion efficiency (PCE) of 12.05% with IDIC-4Cl as an acceptor.

AB - Three small-molecule donors based on dithieno[2,3-d:2ʹ,3ʹ-dʹ]-benzo[1,2-b:4,5-bʹ] dithiophene (DTBDT) unit were designed and synthesized by side chain regulation with chlorinated or/and sulfurated substitutions (namely ZR1, ZR1-Cl, and ZR1-S-Cl respectively), along with a crystalline non-fullerene acceptor IDIC-4Cl with a chlorinated 1,1-dicyanomethylene-3-indanone (IC) end group. Energy levels, molar extinction coefficients and crystallinities of three donor molecules can be effectively altered by combining chlorination and sulfuration strategies. Especially, the ZR1-S-Cl exhibited the best absorption ability, lowest higher occupied molecular orbital (HOMO) energy level and highest crystallinity among three donors, resulting in the corresponding all-small-molecule organic solar cells to produce a high power conversion efficiency (PCE) of 12.05% with IDIC-4Cl as an acceptor.

U2 - 10.1016/j.jechem.2020.04.041

DO - 10.1016/j.jechem.2020.04.041

M3 - Journal article

VL - 52

SP - 228

EP - 233

JO - Journal of Natural Gas Chemistry

JF - Journal of Natural Gas Chemistry

SN - 2095-4956

ER -

ID: 243064315